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Question

Predict the major product of the reaction shown.

122606_ba44cb33fd144b00b4948c2269b942c1.png

A
o- cyanonitrobenzene & p- cyanonitrobenzene
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B
m- nitrobenzaldehyde
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C
o-cyanonitrobenzenesulphonic acid & p- cyanonitrobenzenesulphonic acid
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D
m- cyanonitrobenzenesulphonic acid
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Solution

The correct option is B m- nitrobenzaldehyde
The carboxylic group is meta directing and ortho-para deactivating group. Thus during the nitration of benzaldehyde, the nitro group get attached to the meta position forming m-nitrobenzaldehyde as a product.
125118_122606_ans_77ec898456f7473d95487e51f1f98b6e.png

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