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Question

Predict the product 'B'

A
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B
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C
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D
None of the above
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Solution

The correct option is D None of the above
First step in the given reaction is electrophilic aromatic substitution reaction.
The NO2 group is a deactivating and meta directing groups. Hence the product 'A' is meta chloro nitrobenzene.

The reagents of the second step tends to nucleophilic substitution reaction on product 'A'.

For SNAr to occur, the electron withdrawing group should present at the ortho or para position of leaving group (Cl).
But here it is at the meta position so the compound 'A' does not undergo nucleophilic reaction.


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