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Question

Predict which compound is more reactive with HCl : 2-methyl propene or propene.

A
2-methylpropene
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B
Propene.
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C
Both does't react
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D
None of these
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Solution

The correct option is A 2-methylpropene
2methyl propene is more reactive with HCl than propene as the +I effect of methyl groups makes double bond more electron rich and during electrophilic addition, a tertiary carbocation intermediate is obtained which is more stable than secondary carbocation intermediate.

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