Pressure of a mixture of 4g of O2 and 2g of H2 confined in a bulb of 1 litre at 0oC is:
V=1L
T=273K
Let us find the Partial pressure of O2.
No. of moles =4/32=0.125moles
P1 =nRTv= 0.125×0.082×2731=2.80atm
Now let us find the partial pressure of H2.
P2= nRTv=1×0.082×2731=22.386atm
Total pressure of the mixture = 2.80+22.38=25.18atm.
Therefore 25.18≈ 25.21