Primary amine $(R N H_{2})$ reacts with nitrous acid to give :

R N H_{3}^{+} N O_{2}

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ROH

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ROR

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None of these

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Solution

The correct option is B ROH
$1^{o}$ aliphatic amines on reaction with $H N O_{2}$ from alcohol and evolve $N_{2}$
$R N H_{2} + H O N O N a N O_{2} - H C l - ------- \to R O H + N_{2} + H_{2}$

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Which of the following amine will not react with nitrous acid to give nitrogen

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