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Nucleophilic Addition at the Carbonyl

Primary amine...

Question

Primary amines on heating with_and_ form alkyl isocyanides.

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Solution

chloroform, KOH or NaOH

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Q. Primary amines on heating with

C H {C l}_{3}, K O H

N a O H

form alkyl isocyanides. This reaction is called:

Q. On heating alkyl isocyanide to 250

^{o}

C ............... is formed.

Q. Assertion :Alkyl isocyanide can be prepared by carbyl amine reaction. Because Reason: Ethyl amine when heated with chloroform in presence of alcoholic

K O H

, alkanamide is formed.

Reaction of alkyl halides with ammonia to form a mixture of primary,secondary and tertiary amine is:

Q. Primary amines can be exclusively formed by ammonolysis of alkyl halides.

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Nucleophilic Addition at the Carbonyl

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