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Question

Propanal on treatment with dilute sodium hydroxide gives:

A
CH3CH2CH2CH2CHO
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B
CH3CH2CH(OH)CH2CH2CHO
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C
CH3CH2CH(OH)CH(CH3)CHO
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D
CH3CH2COOH
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Solution

The correct option is C CH3CH2CH(OH)CH(CH3)CHO
Aldol condensation occurs in aldehydes having α-hydrogen with a dilute base to give β-hydroxy aldehydes called aldols. This reaction is most commonly known as aldol condensation.

Propanal on treatment with sodium hydroxide undergoes aldol reaction.
2CH3CH2CHODil. NaOH, 5oC−−−−−−−−−CH3CH2CH(OH)CH(CH3)CHO

Hence, option (c) is the correct answer.

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