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Question

Propane nitrile may be prepared by heating:

A
propyl alcohol with KCN
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B
ethyl alcohol with KCN
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C
propyl chloride with KCN
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D
ethyl chloride with KCN
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Solution

The correct option is A ethyl chloride with KCN
KCN will provide one carbon to propane nitrile hence, starting material will have two carbon atoms.

C2H5Cl+KCNC2H5CN+KCl

By reaction of KCN with ethylchloride, propane nitrile forms as major product.

Option D is correct.

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