Let A be a skew-symmetric matrix.
Then, by definition A′=−A
The (i,j)th element of A′ = the (i,j)th element of (−A).
⟹ The (j,i)th element of A = − the (i,j)th element of A
For the diagonal elements, i=j
Therefore, the (i,i)th element of A = − the (i,i)th element of A
⟹ the (i,i)th element of A=0
Hence, the diagonal elements of a skew-symmetric matrix are all zero.