Consider the given expression,
n∑r=03rnCr=4n
Binomial theorem,
n∑r=0nCran−rbr=(a+b)n
Put a=3 and b=1, we get
n∑r=0nCr1n−r3r=(1+3)n
n∑r=0nCr3r=(4)n
n∑r=03rnCr=(4)n
Hence, proved