Prussian blue colour is obtained by mixing together an aqueous solution of Fe3+ salt with :
A
ferrocyanide
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B
hydrogen cyanide
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C
sodium cyanide
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D
All of the above.
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Solution
The correct option is A ferrocyanide Reddish brown precipitate of ferric hydroxide dissolves in hydrochloric acid and ferric chloride is formed. Fe(OH)3+3HCl→FeCl3+3H2O
When the solution containing ferric chloride is treated with potassium ferrocyanide solution a blue precipitate/colouration is obtained. The colour of the precipitate is Prussian blue. It is ferric ferrocyanide FeCl3+3K4[Fe(CN)6]Potassium ferrocyanide→Fe[Fe(CN)6]3Prussian Blue Precipitate+12KCl