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Question

Prussian blue colour is obtained by mixing together an aqueous solution of Fe3+ salt with :

A
ferrocyanide
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B
hydrogen cyanide
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C
sodium cyanide
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D
All of the above.
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Solution

The correct option is A ferrocyanide
Reddish brown precipitate of ferric hydroxide dissolves in hydrochloric acid and ferric chloride is formed.
Fe(OH)3+3HClFeCl3+3H2O
When the solution containing ferric chloride is treated with potassium ferrocyanide solution a blue precipitate/colouration is obtained. The colour of the precipitate is Prussian blue. It is ferric ferrocyanide
FeCl3+3K4[Fe(CN)6]Potassium ferrocyanideFe[Fe(CN)6]3Prussian Blue Precipitate+12KCl

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