Pure Nitrogen can be obtained by passing ammonia vapours over heated copper (II) oxide (CuO).
Ammonia reacts with copper (II) oxide to form pure nitrogen.
2NH3(g)+3CuO(s)→N2(g)+3Cu(s)+3H2O(g)
Pure Nitrogen can also be preparing the thermal decomposition of azides, which can be prepared as:
N2O+2NaNH2→NaN3+NaOH+NH3
When heated, sodium azide gives
2NaN3→2Na+3N2