The correct option is A 5×109/m3
According to the mass action law, the product of hole concentration nh and free electron concentration ne remains constant at constant temperature.
Let n′h be the concentration of the holes before doping and n′e be the concentration of the free electrons before doping.
Let nh be the concentration of the holes after doping and ne be the concentration of the free electrons after doping
Then, nhne=n′hn′e
(1.5×1016)2=4.5×1022×n′e
n′e=5×109/m3