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Question

Pure water vapour is trapped in a vessel of volume 10 cm3. The relative humidity is 40 %. The vapour is compressed slowly and isothermally. Find the volume of the vapour at which it will start condensing.

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Solution

RH=VPSVP

The point where the vapour start condensing,

VP= SVP

We know P1V1=P2V2

RH×SVP×10=SVP×V2

V2=10RH

= 10 × 0.4

= 4 cm


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