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Byju's Answer
Standard XII
Chemistry
Potassium Permanganate
Pyrolusite is...
Question
Pyrolusite is
M
n
O
2
used to prepare
K
M
n
O
4
. Steps are
M
n
O
2
I
→
M
n
O
2
−
4
I
I
→
M
n
O
−
4
Steps I and II are:
A
Fuse with KOH/ air, electrolytic oxidation
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B
Fuse with KOH/ air, electrolytic reduction
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C
Fuse with
c
o
n
c
.
K
O
H
/
a
i
r
, electrolytic reduction
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D
dissolve in
H
2
O
, oxidation
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Solution
The correct option is
A
Fuse with KOH/ air, electrolytic oxidation
Reactions with fused KOH in the presence of water-
2
M
n
O
2
+
4
K
O
H
+
O
2
→
2
K
2
M
n
O
4
+
2
H
2
O
The potassium manganate is then be converted into permanganate by
electrolytic oxidation
in alkaline media:
K
2
M
n
O
4
+
H
2
O
+
K
M
n
O
4
+
K
O
H
+
1
/
2
H
2
Option A is correct.
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Q.
Pyrolusite in
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