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Question

Pyrolusite is MnO2 used to prepare KMnO4. Steps are


MnO2IMnO24IIMnO4

Steps I and II are:

A
Fuse with KOH/ air, electrolytic oxidation
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B
Fuse with KOH/ air, electrolytic reduction
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C
Fuse with conc.KOH/air, electrolytic reduction
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D
dissolve in H2O, oxidation
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Solution

The correct option is A Fuse with KOH/ air, electrolytic oxidation
Reactions with fused KOH in the presence of water-
2MnO2+4KOH+O22K2MnO4+2H2O

The potassium manganate is then be converted into permanganate by electrolytic oxidation in alkaline media:

K2MnO4+H2O+KMnO4+KOH+1/2H2
Option A is correct.

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