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Q.1. When a co-ordination compound CrCl3. 6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write
(i) Structural formula of the complex.
(ii) IUPAC name of the complex.

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Solution

CrCl3.6NH33molAgCl
Primary linkage=3
Secondary linkage=6
Coordination number=6
Complex:-
[Cr(NH3)6]Cl3
Oxidation state of Cr
=x+0×61×3=0
x=+3
Name=hexaaminechromium(III)chloride

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