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Question

Q) What happens when:
a) Ethane reacts with bromine
water
b) Methane reacts with Chlorine
c) Ethanol reacts with acidified potassium dichromate.

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Solution

a) Br2/H2O decolurises only alkene and alkane has no reaction with it.b) Methane undergoes substitution reaction with chlorine when reacts in the presenceof sunlight.CH4 +Cl2 hν CH3Cl +HClMethane MethylchlorideCH3Cl +Cl2 hν CH2Cl2 +HCl Methylene chlorideCH2Cl2 + Cl2 hν CHCl3 +HCl ChloroformCHCl3 + Cl2 hν CCl4 +HCl Carbontetrachloridec) Ethanol reacts with acidified potassium dichromate giving ethanoic acid through the formation of ethanalCH3CH2OH (O) CH3CHO (O) CH3COOH Ethanol Ethanal Ethanoic acid

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