Dear Student,
1. air around us is a mixture of gases
2. Water is a compound because it contains H and O in a fixed ratio of 2:1 and also the compound H2O shows properties different from constituent elements H and O.
3.Iron - element
Sea water - mixture
Milk - mixture
4.No, the naturally occurring material around us in not chemically pure substance because the air around us is a mixture of gases , sea water is mixture of ions , salts and water
Regards!