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Question

Quantum numbers of the electrons are given
(i) n=4,ms=−12

(ii) n=3,l=0
(iii) n=2,l=1
(iv) n=2,l=0
How many electrons in an atom may have these quantum numbers?

A
16,2,6,2
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B
32,18,8,8
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C
16,6,8,6
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D
16,2,6,4
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Solution

The correct option is A 16,2,6,2

Option A is correct

Solution:

Total number of electrons in n shell =2n2
total number of electrons in a orbitals = 2
(a) n=4,ms=1/2
total number of electrons in n = 4 shell=2(4)2=2× 16=32
but we know, there are two spin quantum number positive spin and negative spin .
hence, half of electrons are positive spin and half of electrons are negative spin .
so, 16 electrons have ms/=1/2
(b) n = 3 , l = 0
it is 3s orbital . so, number of electrons in 3s orbital = 2

(C) n=2, l=1

2p=6

as p shell have 3 orbital and 1 orbital can accommodate 2 electrons.

Option A is correct answer


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