The correct option is A Haemoglobin
The quaternary structure of proteins is observed in haemoglobin. It is composed of four subunits - two subunits of α type and two subunits of β type.
Histones are proteins that help in the packaging of DNA. Elastin is a protein that provides elasticity to several organs. Globulins are proteins found in our blood. Histone, elastin and globulins do not have tertiary structures.