Let the mass of the sample is 100g.
Mass of gold = 90g
Mass of copper = (100-90) = 10g
One gram of gold sample will contain 90100=0.9 g of gold
Number of moles of gold =Mass of goldAtomic mass of gold
=0.9197=0.0046
One mole of gold contains NA atoms =6.022×1023
∴ 0.0046 mole of gold will contain =0.0046×6.022×1023
=2.77×1021