Mass of silver = m g
Mass of gold =m100g
Atomic mass of Ag = 108 u
Atomic mass of Au = 197 u
Number of atoms of silver =MassAtomic mass×NA=m108×NA
Number of atoms of gold =m100×197×NA
Ratio of number of atoms of gold to silver
=Au:Ag=m100×197×NA:m108×NA
=108:100×197=108:19700=1:182.41