Quinhydrone electrode is sometimes used to find the pH of a solution. It is based on the following
If standard electrode potential is 0.70 V. If in a particular solution, the electrode potential is found to be0.58V, the pH of the solution is
A
2
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B
4
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C
6
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D
8
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Solution
The correct option is A 2 For the given electrode reaction E=E∘−0.05912log[1[H+]2] =E∘+0.0591log[H+] =E∘−0.0591pH ∴0.58=0.70−0.0591pH or, pH=0.120.059=2