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Question

Quinhydrone electrode is sometimes used to find the pH of a solution. It is based on the following

If standard electrode potential is 0.70 V. If in a particular solution, the electrode potential is found to be 0.58V, the pH of the solution is

A
2
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B
4
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C
6
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D
8
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Solution

The correct option is A 2
For the given electrode reaction
E=E0.05912log[1[H+]2]
=E+0.0591 log[H+]
=E0.0591 pH
0.58=0.700.0591 pH
or, pH=0.120.059=2

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