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Byju's Answer
Standard XII
Chemistry
Assigning Oxidation Numbers
R - O||C - NH...
Question
R
−
O
|
|
C
−
N
H
2
+
x
N
a
O
H
+
B
r
2
⟶
R
−
N
H
2
+
2
N
a
B
r
+
N
a
2
C
O
3
+
H
2
O
Number of moles of
N
a
O
H
used in above Hoffmann bromamide reaction is:
A
3
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B
4
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C
5
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D
6
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Solution
The correct option is
B
4
As refer to IMAGE
01
, this is Hoffmann Bromamide degradation reaction.
Mechanism is shown in IMAGE
02
.
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0
Similar questions
Q.
How many moles of
K
O
H
are required per mole of
R
–
N
H
2
in the balanced reaction?
R
–
N
H
2
+
C
H
C
l
3
+
K
O
H
→
R
−
⊕
N
⊖
C
+
K
C
l
+
H
2
O
Q.
In the Hofmann bromamide degradation reaction, the number of moles of
N
a
O
H
and
B
r
2
used per mole of amine produced are:
Q.
In the Hofmann bromamide degradation reaction, the number of moles of
N
a
O
H
and
B
r
2
used per mole of amine produced are:
Q.
The intermediate formed during the reaction of
R
−
O
|
|
C
−
N
H
2
with
B
r
2
and
K
O
H
are:
Q.
Indicate which nitrogen compound amongst the following would undergo Hoffmann reaction (i.e., reaction with
B
r
2
and strong KOH) to furnish the primary amine (R -
N
H
2
)?
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