Electrophilic Substitution Reactions of Haloarenes
Rank in the o...
Question
Rank in the order of increasing acidic strength:
A
A<B<C
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B
A<C<B
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C
B<A<C
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D
B<C<A
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Solution
The correct option is CB<A<C The greater I effect is favorable or greater acidic strength. The −I effect of aldehyde group is greater than the ester group. Due to this C will be most acidic. In A and B, B will be less acidic as it has −I effect sort of localized due to ester group being on a single carbon. In A it is more delocalized is not effective on more by adjacent carbons.