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Question

Rank in the order of increasing acidic strength:
989427_63e1775a91b94959b8f7da8cb92ff238.PNG

A
A<B<C
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B
A<C<B
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C
B<A<C
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D
B<C<A
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Solution

The correct option is C B<A<C
The greater I effect is favorable or greater acidic strength. The I effect of aldehyde group is greater than the ester group. Due to this C will be most acidic. In A and B, B will be less acidic as it has I effect sort of localized due to ester group being on a single carbon. In A it is more delocalized is not effective on more by adjacent carbons.
Hence, the required order is- B<A<C.

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