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Question

Rank the transition states that occur during the following reaction steps in order of increasing stability (least most stable)
1.H3C+OH2CH+3+H2O
2. (CH3)3C+OH2(CH3)3C++H2O
3. (CH3)2C+OH2(CH3)2CH++H2O

A
1<2<3
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B
2<3<1
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C
1<3<2
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D
2<1<3
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Solution

The correct option is D 1<3<2
The equilibrium constant of reactions is high if the carbocation formed is stable.
3ocation>2ocation>1ocation [stability]
(1) CH3OH2CH31o+H2O
(2) (CH3)3COH2(CH3)33oC+H2O
(3) (CH3)2CoplusOH2(CH3)2C2oH2O
So, 2>3>1 .

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