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Question

Ratio of effusion of a sample of ozonized oxygen is 0.95 times the ratio of pure oxygen. Determine the percentage of ozone in the ozonized sample.

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Solution

Diffusion rates are inversely proportional to the square root of the molar masses.

Since the ozonised gas diffuses slower than O2, it must have a higher molar mass which is reasonable since ozone is O3


MW ozonised gas = 32g/mole /0.982 =33.32g/mole

You have a mixture of O2 with a molar mass of 32 g/mole and ozone with a molar mass of 48 g/mole

Let X be the mole fraction that is O2. 1 - X is the mole fraction that is ozone

X32g/mole+(1X)48g/mole=33.32g/mole

Solve for X.

(1X)100 = % O3 in the mixture

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