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Question

Reaction, 3ClOClO3+2Cl occurs in following two steps.
I. ClO+ClOK1ClO2+Cl(Slow step)
II. ClO+2ClOk2ClO3+Cl (Fast step)
Then, the rate of given reaction is:

A
k1[ClO]
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B
k1[ClO]2
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C
k2[ClO2][ClO]
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D
k2[ClO]3
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Solution

The correct option is B k1[ClO]2
I. ClO+ClOK3ClO2+Cl(Slow step)
II. ClO+2ClOk2ClO3+Cl (Fast step)
Since, slowest step is the rate determining step. so the rate of reaction =k1[ClO]2.

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