Reaction A-2B-C- product- follows the rate law -d-C-d t - k-A-2False statement regarding the above reaction is -

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Elementary and Complex Reactions

Reaction A+...

Question

Reaction $A + 2 B + C \to p r o d u c t$ , follows the rate law $- \frac{d [C]}{d t} = k {[A]}^{2}$
False statement regarding the above reaction is :

On doubling the conc. of B and C the rate of the reaction remains unaffected

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Reducing the conc. of A to half, the rate becomes one-fourth

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Half life period of the reaction depends upon the conc. of B

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Half life period of the reaction is inversely proportional to the first power conc. of A

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2 A + B + C \to 2 D

K [A] {[B]}^{2}

=

=

=

1^{s t}

0.16 M t o 0.02 M

\to

\begin{matrix} S l . N o & [A]_{0} / M (I n i t i a l c o n c .) & [B]_{0} / M (I n i t i a l c o n c .) & R a t e / (M s e c^{- 1}) 1. & 1.6 \times 10^{- 3} & 5 \times 10^{- 2} & 10^{- 3} 2. & 3.2 \times 10^{- 3} & 5 \times 10^{- 2} & 4 \times 10^{- 3} 3. & 1.6 \times 10^{- 3} & 10^{- 1} & 2 \times 10^{- 3} 4. & 3.2 \times 10^{- 3} & 10^{- 1} & 8 \times 10^{- 3} \end{matrix}

A + B \to C + D

r a t e = k [A]^{\frac{1}{2}} [B]^{\frac{1}{2}}

1 M

A

B

A

0.25 M

k = 2.303 \times 10^{- 3} {sec}^{- 1}

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