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Question

Reaction between formaldehyde and benzaldehyde in presence of concentrated NaOH is known as:

A
Cannizzaro’s reaction
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B
Cross Cannizzaro’s reaction
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C
Cross Aldol condensation
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D
Aldol condensation
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Solution

The correct option is B Cross Cannizzaro’s reaction
• Aldehydes which do not have an α-hydrogen atom, undergo self-oxidation and reduction (disproportionation) reaction on heating with concentrated alkali.

HCHO and C6H5CHO, in presence of conc. NaOH undergo cross Cannizzaro’s reaction.



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