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Question

Reaction of Chlorobenzene with CH3Cl in presence of AlCl3 gives:

A
Toulene
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B
m-chloro toulene
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C
Only o-chloro toulene
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D
Mixture of o- and p-chlorotoulene
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Solution

The correct option is D Mixture of o- and p-chlorotoulene
As Cl group attached to benzene is ortho, para directing so it forms o,p chloro toluene.
This is a Fridel Craft's alkylation reaction.

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