Reaction of $R - C O O H$ with $N_{3} H$ gives $R N H_{2}$ as the main product. The intermediate(s) involved in this reacton is/are :

R N H N H_{2}

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R C O N_{3}

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R N C O

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R C O N H_{2}

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Solution

The correct options are
B $R C O N_{3}$
C $R N C O$
This reaction is called Schmidt reaction. It involves alkyl migration over the carbon-nitrogen bond in an azide with expulsion of nitrogen.
$R C O O H + H N_{3} H^{+} - - \to R N C O H_{2} O - - \to R N H_{2}$
The intermediates involved can be seen in the mechanism provided.

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