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Question

Reactivity of the given compound with the following Grignard reagent in the decreasing order is:
(i)MeMgBr (ii)EtMgBr (iii)Me2CH−MgBr (iv)Me3C−MgBr
244467.PNG

A
(i)>(ii)>(iii)>(iv)
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B
(iv)>(iii)>(ii)>(i)
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C
(i)>(ii)>(iv)>(iii)
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D
(iv)>(ii)>(iii)>(i)
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Solution

The correct option is A (i)>(ii)>(iii)>(iv)
Since the Grignard reagent reacts by SN2 mechanism, the reactivity order of SN2 reaction is 1oRMgX>2oRMgX>3oRMgX. Hence, the answer is option A.
370116_244467_ans.png

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