Reactivity of the given compound with the following Grignard reagent in the decreasing order is: (i)MeMgBr(ii)EtMgBr(iii)Me2CH−MgBr(iv)Me3C−MgBr
A
(i)>(ii)>(iii)>(iv)
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B
(iv)>(iii)>(ii)>(i)
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C
(i)>(ii)>(iv)>(iii)
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D
(iv)>(ii)>(iii)>(i)
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Solution
The correct option is A(i)>(ii)>(iii)>(iv) Since the Grignard reagent reacts by SN2 mechanism, the reactivity order of SN2 reaction is 1oRMgX>2oRMgX>3oRMgX. Hence, the answer is option A.