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Question

Reactivity order of halides for dehydrohalogenation is :

A
RF>RCl>RBr>RI
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B
RI>RBr>RCl>RF
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C
RI>RCl>RBr>RF
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D
RF>RI>RBr>RCl
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Solution

The correct option is B RI>RBr>RCl>RF
F, Cl, Br, I belong to the same group orderly. Atomic radii go on increasing as the nuclear charge increases in proceeding downwards in a group.
The decreasing order of bond length CI>CBr>CCl>CF

The order of bond dissociation energy RF>RCl>RBr>RI.

During dehydrohalogenation CI bond breaks more easily than CF bond.
So reactivity order of halides. RI>RBr>RCl>RF

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