Rearrange the following in the increasing order of acidic strength. (i) benzoic acid (ii) p-methoxybenzoic (iii) o-methyoxybenzoic
A
i<ii<iii
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B
iii<i<ii
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C
ii<i<iii
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D
iii<ii<i
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Solution
The correct option is Diii<ii<i The order of acidity will be-
O-methoxybenzoic acid > Benzoic acid> P -methoxybenzoic acid.
Reason-
[1] As the paramethoxybenzoic acid has an electron donating group(−OCH3) at the para position so this group will increase the electron density in the ring that will unstable the negative charge that is left after the removal of H+.