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Question

Rearrange the following in the increasing order of acidic strength.
(i) benzoic acid
(ii) p-methoxybenzoic
(iii) o-methyoxybenzoic

A
i<ii<iii
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B
iii<i<ii
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C
ii<i<iii
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D
iii<ii<i
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Solution

The correct option is D iii<ii<i
The order of acidity will be-
O-methoxybenzoic acid > Benzoic acid> P -methoxybenzoic acid.
Reason-
[1] As the paramethoxybenzoic acid has an electron donating group(OCH3) at the para position so this group will increase the electron density in the ring that will unstable the negative charge that is left after the removal of H+.

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