Reddish brown colouration when neutral FeCl3 is added to the CH3COO− aqueous solution is due to the formation of [Fe3(OH)2(CH3COO)6]+ .
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Solution
Reddish brown colouration when neutral FeCl3 is added to the CH3COO− aqueous solution is due to the formation of [Fe3(OH)2(CH3COO)6]+. 3FeCl3+6CH3COOH+2H2O+H+→[Fe3(OH)2(CH3COO)6]++9HCl