Refer to the following experimental data-Half Reaction EoI- Mg- Mg 2- -2 e -2-37VII- Mn- Mn 2- -2 e -1-03VIII- H 2 - 2 H - -2 e -0-00VIV- Cu- Cu 2- -2 e -0-16VWhich of the following reactions is spontaneous-

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Standard XII

Chemistry

SHE

Refer to the ...

Question

Refer to the following experimental data.
Half Reaction $E_{o}$
I. $M g \to {M g}^{2 +} + 2 e^{-}$ 2.37V
II. $M n \to {M n}^{2 +} + 2 e^{-}$ 1.03V
III. $H_{2} \to 2 H^{+} + 2 e^{-}$ 0.00V
IV. $C u \to {C u}^{2 +} + 2 e^{-}$ -0.16V
Which of the following reactions is spontaneous?

{M n}^{2 +} + H_{2} \to

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M g + {M n}^{2 +} \to

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{M g}^{2 +} + M n \to

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C u + 2 H^{+} \to

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Solution

The correct option is B $M g + {M n}^{2 +} \to$
The reaction will be spontaneous for which $E_{c e l l}$ is $+ v e$ value.
for $M g + {M n}^{2 +} ⟶ E_{c e l l} = 2.73 - 1.03 = 1.34 \Rightarrow + v e$
$∴$ spontaneous

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Similar questions

Q. Refer to the following experimental data.

Half Reaction	Eo
I. $M g \to {M g}^{2 +} + 2 e^{-}$	2.37V
II. $M n \to {M n}^{2 +} + 2 e^{-}$	1.03V
III. $H_{2} \to 2 H^{+} + 2 e^{-}$	0.00V
IV. $C u \to {C u}^{2 +} + 2 e^{-}$	-0.16V

What will be the standard reduction potential for the reaction:

M g + M n^{2 +} \to M g^{2 +} + M n

Half Reaction	Eo
I. $M g \to {M g}^{2 +} + 2 e^{-}$	2.37V
II. $M n \to {M n}^{2 +} + 2 e^{-}$	1.03V
III. $H_{2} \to 2 H^{+} + 2 e^{-}$	0.00V
IV. $C u \to {C u}^{2 +} + 2 e^{-}$	-0.16V

From the above experimental data which of the following represents a spontaneous process?

Half Reaction	Eo
I. $M g \to {M g}^{2 +} + 2 e^{-}$	2.37V
II. $M n \to {M n}^{2 +} + 2 e^{-}$	1.03V
III. $H_{2} \to 2 H^{+} + 2 e^{-}$	0.00V
IV. $C u \to {C u}^{2 +} + 2 e^{-}$	-0.16V

From the above experimental data what will be the standard reduction potential which represents spontaneous process?

Q. Rank the following elements by increasing ease of oxidation with most easily oxidized LAST:

C d, C u, N i, F e

Standard Reduction Potentials at

25^{\circ} C

Half-Reaction	$E^{\circ} (V)$
$F_{2} + 2 e^{-} \to 2 F^{-}$	$2.87$
$A g^{2} + e^{-} \to A g^{+}$	$1.99$
$C o^{3 +} + e^{-} \to C o^{2 +}$	$1.82$
$H_{2} O_{2} + 2 H^{+} + 2 e^{-} \to 2 H_{2} O$	$1.78$
$M n O_{4}^{-} + 4 H^{+} + 3 e^{-} \to M n O_{2} + 2 H_{2} O$	$1.68$
$2 e^{-} + 2 H^{+} + I O_{4}^{-} \to I O_{3}^{-} + H_{2} O$	$1.60$
$M n O_{4}^{-} + 8 H^{+} + 5 e^{-} \to M n^{2 +} + 4 H_{2} O$	$1.51$
$A u^{3 +} + 3 e^{-} \to A u$	$1.50$
$C l_{2} + 2 e^{-} \to 2 C l^{-}$	$1.36$
$O_{2} + 4 H^{+} + 4 e^{-} \to 2 H_{2} O$	$1.23$
$M n O_{2} + 4 H^{+} + 2 e^{-} \to M n^{2 +} + 2 H_{2} O$	$1.21$
$B r_{2} + 2 e^{-} \to 2 B r^{-}$	$1.09$
$N O_{3}^{-} + 4 H^{+} + 3 e^{-} \to N O + 2 H_{2} O$	$0.96$
$C l O_{2} + e^{-} \to C l O_{2}$	$0.954$
$2 H g^{2 +} + 2 e^{-} \to H g_{2}^{2 +}$	$0.91$
$A g^{+} + e^{-} \to A g$	$0.80$
$H g_{2}^{2 +} + 2 e^{-} \to 2 H g$	$0.80$
$F e^{3 +} + e^{-} \to F e^{2 +}$	$0.77$
$O_{2} + 2 H^{+} + 2 e^{-} \to H_{2} O_{2}$	$0.68$
$M n O_{4}^{-} + e^{-} \to M n O_{4}^{2 -}$	$0.56$
$I_{2} + 2 e^{-} \to 2 I^{-}$	$0.54$
$C u^{+} + e^{-} \to C u$	$0.52$
$O_{2} + 2 H_{2} O + 4 e^{-} \to 4 O H^{-}$	$0.40$
$C u^{2 +} + 2 e^{-} \to C u$	$0.34$
$A g C l + e^{-} \to A g + C l^{-}$	$0.22$
$C u^{2 +} + e^{-} \to C u^{+}$	$0.16$
$2 H^{+} + 2 e^{-} \to H_{2}$	$0.00$
$F e^{3 +} + 3 e^{-} \to F e$	$- 0.036$
$P b^{2 +} + 2 e^{-} \to P b$	$- 0.13$
$N i^{2 +} + 2 e^{-} \to N i$	$- 0.23$
$C d^{2 +} + 2 e^{-} \to C d$	$- 0.40$
$F e^{2 +} + 2 e^{-} \to F e$	$- 0.44$
$C r^{3 +} + e^{-} \to C r^{2 +}$	$- 0.50$
$C r^{3 +} + 3 e^{-} \to C r$	$- 0.73$
$Z n^{2 +} + 2 e^{-} \to Z n$	$- 0.76$
$2 H_{2} O + 2 e^{-} \to H_{2} + 2 O H^{-}$	$- 0.83$
$M n^{2 +} + 2 e^{-} \to M n$	$- 1.18$
$A l^{3 +} + 3 e^{-} \to A l$	$- 1.66$
$H_{2} + 2 e^{-} \to 2 H^{-}$	$- 2.23$
$M g^{2 +} + 2 e^{-} \to M g$	$- 2.37$
$N a^{+} + e^{-} \to N a$	$- 2.71$
$C a^{2 +} + 2 e^{-} \to C a$	$- 2.76$
$B a^{2 +} + 2 e^{-} \to B a$	$- 2.90$
$K^{+} + e^{-} \to K$	$- 2.92$
$L i^{+} + e^{-} \to L i$	$- 3.05$

Q. Find the

△ G^{\circ}

of a galvanic cell with

A g

and

A l

Standard Reduction Potentials at

25^{\circ} C

Half-Reaction	$E^{\circ} (V)$
$F_{2} + 2 e^{-} \to 2 F^{-}$	$2.87$
$A g^{2} + e^{-} \to A g^{+}$	$1.99$
$C o^{3 +} + e^{-} \to C o^{2 +}$	$1.82$
$H_{2} O_{2} + 2 H^{+} + 2 e^{-} \to 2 H_{2} O$	$1.78$
$M n O_{4}^{-} + 4 H^{+} + 3 e^{-} \to M n O_{2} + 2 H_{2} O$	$1.68$
$2 e^{-} + 2 H^{+} + I O_{4}^{-} \to I O_{3}^{-} + H_{2} O$	$1.60$
$M n O_{4}^{-} + 8 H^{+} + 5 e^{-} \to M n^{2 +} + 4 H_{2} O$	$1.51$
$A u^{3 +} + 3 e^{-} \to A u$	$1.50$
$C l_{2} + 2 e^{-} \to 2 C l^{-}$	$1.36$
$O_{2} + 4 H^{+} + 4 e^{-} \to 2 H_{2} O$	$1.23$
$M n O_{2} + 4 H^{+} + 2 e^{-} \to M n^{2 +} + 2 H_{2} O$	$1.21$
$B r_{2} + 2 e^{-} \to 2 B r^{-}$	$1.09$
$N O_{3}^{-} + 4 H^{+} + 3 e^{-} \to N O + 2 H_{2} O$	$0.96$
$C l O_{2} + e^{-} \to C l O_{2}$	$0.954$
$2 H g^{2 +} + 2 e^{-} \to H g_{2}^{2 +}$	$0.91$
$A g^{+} + e^{-} \to A g$	$0.80$
$H g_{2}^{2 +} + 2 e^{-} \to 2 H g$	$0.80$
$F e^{3 +} + e^{-} \to F e^{2 +}$	$0.77$
$O_{2} + 2 H^{+} + 2 e^{-} \to H_{2} O_{2}$	$0.68$
$M n O_{4}^{-} + e^{-} \to M n O_{4}^{2 -}$	$0.56$
$I_{2} + 2 e^{-} \to 2 I^{-}$	$0.54$
$C u^{+} + e^{-} \to C u$	$0.52$
$O_{2} + 2 H_{2} O + 4 e^{-} \to 4 O H^{-}$	$0.40$
$C u^{2 +} + 2 e^{-} \to C u$	$0.34$
$A g C l + e^{-} \to A g + C l^{-}$	$0.22$
$C u^{2 +} + e^{-} \to C u^{+}$	$0.16$
$2 H^{+} + 2 e^{-} \to H_{2}$	$0.00$
$F e^{3 +} + 3 e^{-} \to F e$	$- 0.036$
$P b^{2 +} + 2 e^{-} \to P b$	$- 0.13$
$N i^{2 +} + 2 e^{-} \to N i$	$- 0.23$
$C d^{2 +} + 2 e^{-} \to C d$	$- 0.40$
$F e^{2 +} + 2 e^{-} \to F e$	$- 0.44$
$C r^{3 +} + e^{-} \to C r^{2 +}$	$- 0.50$
$C r^{3 +} + 3 e^{-} \to C r$	$- 0.73$
$Z n^{2 +} + 2 e^{-} \to Z n$	$- 0.76$
$2 H_{2} O + 2 e^{-} \to H_{2} + 2 O H^{-}$	$- 0.83$
$M n^{2 +} + 2 e^{-} \to M n$	$- 1.18$
$A l^{3 +} + 3 e^{-} \to A l$	$- 1.66$
$H_{2} + 2 e^{-} \to 2 H^{-}$	$- 2.23$
$M g^{2 +} + 2 e^{-} \to M g$	$- 2.37$
$N a^{+} + e^{-} \to N a$	$- 2.71$
$C a^{2 +} + 2 e^{-} \to C a$	$- 2.76$
$B a^{2 +} + 2 e^{-} \to B a$	$- 2.90$
$K^{+} + e^{-} \to K$	$- 2.92$
$L i^{+} + e^{-} \to L i$	$- 3.05$

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Half Reaction	$E_{o}$
I. $M g \to {M g}^{2 +} + 2 e^{-}$	2.37V
II. $M n \to {M n}^{2 +} + 2 e^{-}$	1.03V
III. $H_{2} \to 2 H^{+} + 2 e^{-}$	0.00V
IV. $C u \to {C u}^{2 +} + 2 e^{-}$	-0.16V

Refer to the following experimental data.Half ReactionEoI. Mg→Mg2++2e−2.37VII. Mn→Mn2++2e−1.03VIII. H2→2H++2e−0.00VIV. Cu→Cu2++2e−-0.16VWhich of the following reactions is spontaneous?

The correct option is B Mg+Mn2+→The reaction will be spontaneous for which Ecellis+ve value.for Mg+Mn2+⟶Ecell=2.73−1.03=1.34⇒+ve ∴ spontaneous

Refer to the following experimental data.
Half Reaction $E_{o}$
I. $M g \to {M g}^{2 +} + 2 e^{-}$ 2.37V
II. $M n \to {M n}^{2 +} + 2 e^{-}$ 1.03V
III. $H_{2} \to 2 H^{+} + 2 e^{-}$ 0.00V
IV. $C u \to {C u}^{2 +} + 2 e^{-}$ -0.16V
Which of the following reactions is spontaneous?

The correct option is B $M g + {M n}^{2 +} \to$
The reaction will be spontaneous for which $E_{c e l l}$ is $+ v e$ value.
for $M g + {M n}^{2 +} ⟶ E_{c e l l} = 2.73 - 1.03 = 1.34 \Rightarrow + v e$
$∴$ spontaneous