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Question

Salicyclic acid is treated with bromine under two different conditions.

Predict the nature of [X] and [Y] in the above reactions


A

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B

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C

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D

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Solution

The correct option is B


Note that when some activating group, e.g, - OH is present along with COOH in ortho or para position substitution occurs with respect to -OH preferably at the para position due to steric factors. In case the reagent used is strong, the electrophile enters at all possible positions even with the replacement of - COOH group.


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