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Question

Salts of A (atomic mass 15), B (atomic mass 27) and C (atomic mass 48) were electrolyzed using the same amount of charge. It was found that when 4.5 g of A was deposited, the mass of B and C deposited were 2.7 g and 9.6 g. The valencies of A, B and C respectively.

A
1,3 and 2
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B
3,1 and 3
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C
2,6 and 3
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D
2,3 and 2
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Solution

The correct option is C 2,6 and 3
According to Faraday's second law,
mass of Aeq. mass of A=mass of Beq. mass of B=mass of Ceq. mass of C
4.515/n1=2.727/n2=9.648/n3 (Here n1,n2,n3 represents velency)
0.3n1=0.1n2=0.2n3

n1:n2:n3=2:6:3

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