Multi-Electron Configurations and Orbital Diagrams
Second neares...
Question
Second nearest neighbour in CsCl solid
ans: 6
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Solution
The CsCl is an ionic structure showing two interpenetrating simple cubic lattices, one for each kind of ion. It has a coordination number 8. There are six ions of the same charge from a given ion at a distance of ∛r where r is the distance between the anion and cation (e.g., rCs^+ + rCl^-). From diagram there are six ions of opposite charge in next-nearest contact, directly through the six faces of the cube at a distance of a where a is the side of the unit cell. From Pythagoras the body diagonal of the unit cell is ∛a = 2r hence a = (2/∛ r) = 1.15r