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Question

Select the correct code for the following repulsion orders, according to VSEPR theory
(I) lone pair-lone pair > lone pair-bond pair
(II) lone pair-bond pair > bond pair-bond pair
(III) lone pair-lone pair > bond pair-bond pair
(IV) lone pair-bond pair > lone pair-lone pair

A
I,II and III
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B
II and IV
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C
I,II and IV
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D
All
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Solution

The correct option is A I,II and III
According to the VSEPR theory, lone pairs of electrons occupy more space than bonding pairs. As a consequence, this is an order of the magnitude of repulsion.

lplp>lpbp>bpbp

  • Greatest repulsion is between 2 lone pairs.
  • Followed by repulsion between one lone pair and one bonding pair.
  • The weakest repulsion is between 2 bonding pairs, the magnitude of repulsion between bonding pairs of electrons depends on the EN difference between a central atom and the other atoms.

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