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Question

Select the correct IUPAC Name of K2[Cd(CN)4] :

A
potassium tetracyanidocadmate(II)
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B
potassium tetracyanidocadmate(III)
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C
both A and B
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D
none of these
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Solution

The correct option is A potassium tetracyanidocadmate(II)
Option (D) is correct. The correct IUPAC name of K2[Cd(CN)4] is potassium tetracyanocadmate(II).

In this complex there are four CN so they are named as tetracyanido and cyanide ligand has -1 charge. So the cadmium overall has -2 charge, so the name of cadmium with -ate followed by the charge in roman letters.

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