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Question

Select the correct option for Column I and Column II:
Column IColumn II(a) NH2(p) μ=0(b) NH+4(q) planar(c) I3(r) dx2y2 is involved in hybridisation(d) PCl6(s) d2x is involved in hybridisation(e) PCl+2(t) Bent structure

A
(a):q,t (b):t (c):q,s (d):p,r (e):s,t
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B
None of the above
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C
(a):r,t (b):p (c):p,s (d):p,q,s (e):q,t
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D
(a):q,t (b):p (c):p,q,s (d):p,r,s (e):q,t
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Solution

The correct option is D (a):q,t (b):p (c):p,q,s (d):p,r,s (e):q,t
(a): NH2(i) Bent structure
(ii) sp3 hybridisation
(iii) Planar
(iv) μ0,polar

(b): NH+4

(i) Tetrahedral struture
(ii) Non-planar
(iii) sp3 hybridisation
(iv) μ=0
(v)Non-polar

(c): I3


(i) sp3d hybridisation
(ii)d2z is involved in hybridisation
(iii) Linear, planar
(iv) μ=0, Non-polar

(d): PCl6

(i) sp3d2 hybridisation
(ii) dx2y2,d2z is involved in hybridisation
(iii) Non-polar
(iv) μ=0, non-polar

(e) PCl+2

(i) sp3 hybridisation
(ii) Bent structure
(iii) Planar
(iv) μ0, polar

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