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Question

Select the correct order for covalent radii :

A
Octahedral radii > linear radii > tetrahedral radii
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B
Octahedral radii > tetrahedral radii > linear radii
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C
Linear radii > tetrahedral radii > octahedral radii
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D
Tetrahedral radii > octahedral radii > linear radii
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Solution

The correct option is B Octahedral radii > tetrahedral radii > linear radii


1. If the triangular void in a close-packed layer has a sphere directly over it, there results a void with four spheres around it, as shown Such a void is called a tetrahedral void since the four spheres surrounding it are arranged on the corners of a regular tetrahedron.

If R denotes the radius of the four spheres surrounding a tetrahedral void, the radius of the spheres that would just fit into this void is 0.225 R.

(ii) If a triangular void pointing up in one close-packed layer is covered by a triangular void pointing down in the adjacent layer, then a void surrounded by six spheres results . Such a void is called an octahedral void since the six spheres surrounding it lie at the corners of a regular octahedron.

The radius of the sphere that would just fit into an octahedral void in a close-packing is 0.414 R.

Ocathedral radii > tetrahedral radii > linear radii


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