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Question

Select the correct order with respect to the basic character of the transition metal monoxides.

(Atomic number in amu of Ti=22, V=23, Cr=24, Fe=26)

A
VO>CrO>TiO>FeO
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B
CrO>VO>FeO>TiO
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C
TiO>FeO>VO>CrO
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D
TiO>VO>CrO>FeO
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Solution

The correct option is D TiO>VO>CrO>FeO
Oxides of transition metals in low oxidation state +2 and +3 (MO,M2O4,and M2O3) are generally basic except Cr2O3 which is amphoteric in character.

The basic character generally decreases with an increase in atomic number.

The correct order of basic character of the transition metal monoxides is TiO>VO>CrO>FeO

Hence, option D is correct.

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