Select the correct statement(s):- i)Schottky defect is shown by CsCl ii)Frenkel defect is shown by Zns iii)Hexagonal close packing (hcp) & Cubic close packing (ccp) structure has same co-ordination no.12
iv) At high pressure, the co-ordination number increases.
A
i, ii, iii & iv
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B
i, ii, & iv
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C
ii, iii & iv
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D
i,
iii& iv
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Solution
The correct option is A
i, ii, iii & iv
Schottky defect is shown by crystals having higher value of limiting radius ratio (higher coordination number) = 8 in CsCl Frenkel defect is shown by crystals having lower value of limiting radius ratio (lower coordination number)= 4 in ZnS
Hexagonal close packing (hcp) & Cubic close packing (ccp) structure has same packing fraction