In a hypothetical reaction C→Y, the activation energy for the forward and backward reaction is 15 and 9kJmol−1, respectively. The potential energy of X is 10 kJ mol−1. Then Plot of r1/2 vs. concentration.
A
The heat of reaction is 6 kJ.
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B
The potential energy of Y is 16 kJ.
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C
The threshold energy of the reaction is 25 kJ.
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D
The reaction is endothermic.
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Solution
The correct options are A The heat of reaction is 6 kJ. B The potential energy of Y is 16 kJ. C The threshold energy of the reaction is 25 kJ. D The reaction is endothermic. For Reaction X→Y
Ea(f)=15kJmol1Ea(b)=9kJmol1
Heat reaction Ea(f)Ra(b)=159=6kJmol1
Potential energy of Y is = 10 + 6 = 16 kJ
Threshold energy of the reaction = PE of X + Ea(f)