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Question

Select the correct statements:

In a hypothetical reaction CY, the activation energy for the forward and backward reaction is 15 and 9kJmol1, respectively. The potential energy of X is 10 kJ mol1. Then Plot of r1/2 vs. concentration.


A
The heat of reaction is 6 kJ.
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B
The potential energy of Y is 16 kJ.
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C
The threshold energy of the reaction is 25 kJ.
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D
The reaction is endothermic.
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Solution

The correct options are
A The heat of reaction is 6 kJ.
B The potential energy of Y is 16 kJ.
C The threshold energy of the reaction is 25 kJ.
D The reaction is endothermic.
For Reaction XY

Ea(f)=15kJmol1Ea(b)=9kJmol1

Heat reaction Ea(f)Ra(b)=159=6kJmol1

Potential energy of Y is = 10 + 6 = 16 kJ

Threshold energy of the reaction = PE of X + Ea(f)

= 10 kJ + 15 kJ

= 25 kJ

The reaction is endothermic because Ea(f)>Ea(b)

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